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Date:         Mon, 12 Sep 94 10:01:57 CDT
Sender:       Vanagon Mailing List <vanagon@vanagon.com>
From:         "J. Walker" <JWALKER@ua1vm.ua.edu>
Subject:      oh no! Slick 50 again!!! :)

ok, boys and girls. i started NOT to do this, but decided what the heck. this is an article that appears in the October 1994 issue of Motortrend magazine. since they are a somewhat respectible publication (?), albeit prone IMHO toward Detroit-is-Great! sentiments, it is very likely that they know more about automobiles than i do. hell, bill clinton probably knows more about automobiles than i do. :) anyway, here goes: -----------------------------------------------------------------------------

Car Care by Rik Paul (Motor Trend magazine, October 1994. page 148.)

Navigating the Maze of Friction-Reducing Formulas

One of the biggest phenomenons to hit the engine-care scene over the last few years has been the wave of friction-reducint, anti-wear engine treatments. Over the years, we've received more reader questions about these products than any other car-care subject. It also seems as though we receive notices of new entries in this category almost weekly. The main claim of these products is the ability to reduce internal engine wear ... particularly during the critical cold-start period ... resulting in longer service life. Some also make additional claims regarding increased performance and fuel economy resulting from the reduced friction.

To the average consumer, all of the hype, claims, and counter-claims can seems as confusing to navigate as a bayou. Part of the prolem is due to the fact that objectively evaluating these products in order to substantiate their anti-wear claims is almost impossible without prohibitively expensive lab tests. Which, of course, provides fertile ground for exaggerated assertions and inflated statistics. Meanwhile, public perception of these friction-reducers ranges from miracle treatments to modern-day snake oils. The truth, however, probably rests somewhere in between.

One of the common additives found in many formulas is a polymer called polytetrafluoroethylene, or PTFE. Origianlly discovered by DuPont in the late '30s, it's commonly known by that manufacturer's trade name, Teflon, and is considered to be the most slippery solid substance known to man. As an engine treatment, it's added to engine oil as microscopic particles. The particles purportedly bond to internal engine surfaces, reducing the friction of moving parts, such as bearings and rings, thereby decreasing wear and improving efficiency.

PTFE's history as an engine oil additive, though, is spotty, due largely to the fact that not all formulas are created equal. It was first used for this application in the '70s, but by 1980, Du Pont had decided to discontinue Teflon sales to oil-additive manufacturers, a ban that remained in place for about a decade. One problem was that anyone could ... and still can ... buy the polymer in bulk, add it to carrier oil, and package it as their own formula, without sufficient technical expertise to make it work. In some products, the PTFE reportedly separated from the oil and settled in the oil pan. Plus, there was concern over particle build-up clogging oil filters and passages. Such problems with these early versions has left a stigma that still lingers.

Petrolon got the current bandwaon rolling about five years ago when it introduced a reformulated Slick 50 Engine Treatment. The product has been heavily marketed and is currently the category's undisputed sales leader. In fact, in '92, it held a 90-percent share of the engine- treatment market. Petrolon claims that Slick 50 reduces engine wear at start-up and during operation for over 50,000 miles.

A few years ago, the company also made claims regarding improvements in performance and fuel economy, but in 1992, the National Advertising Division of the Council of Better Business Bureaus asked Petrolon to discontinue such assertions due to lack of substantiating evidence. Although Petrolon was targeted for this review largely because of its size, the same scrutiny should be applied to any of the products in this category.

As in most current products, the PTFE particles in Slick 50 are maintained in a colloidal suspension, in which they are electrically charged to repel each other. This keeps them from bonding or coagulating, which not only keeps the PTFE from setting out of the oil, but also prevents the clogging of oil filters.

This charge is gradually lost, and sources vary on how long PTFE remains effective. Although Slick 50 claims it reduces wear over 50,000 miles, others say the real value of PTFE is more short-term, with its effectiveness possibly beginning to erode after 10,000 to 20,000 miles. Hilton Oil Corporation, the company that markets T-Plus, another compound containing PTFE, says that "over a period of time and mileage, PTFE levels in the engine are gradually reduced." Subsequently, the company offers a T-Plus Booster to replenish the PTFE.

Until recently, DuPont has maintained a neutral stance on the use of Teflon as an oil additive, neither confirming nor promoting any claimed benefits. Last year, however, Petrolon and DuPont signed a technology- sharing agreement to cooperate in development of new lubricant formulas and other products incorporating PTFE, as well as the possible development of new polymers and co-polymers for this purpose.

What about the problem of clogged oil filters? The Fram Filter Division of Allied-Signal Aftermarket Group conducted a study in 1992 to determine just this point, specifically targeting Slick 50 and a competitor named Tufoil. The study found that the PTFE particles in those formulas freely flow through typical oil filters used on passenger-car engines, with no danger of clogging. The average size of a PTFE particle is about 0.2 to 0.3 microns, which is well below the 35-micron pore size of typical passenger-car oil filters. Petrolon, however, advises that use of Slick 50 isn't recommened with systems that filter particles 5 microns or smaller.

Slick 50 shares the scene with numerous other products, each with its own formula and claims. T-Plus, for instance, claims it has 50 percent more PTFE, while QMI claims 10 times more PTFE than its "nearest competitor." Petrolon counters that an engine can only use so much PTFE, just as a human body can only absorb so much vitamin C.

Products such as Tufoil and OEM combine PTFE with molybdenum, a soluble heavy-metal compound, which their manufacturers claim provides increased anti-wear characteristics. Meanwhile, a company called Engine-slick advertises that it uses a unique interface bonding technique instead of the more common collodial suspension, which "interlocks Teflon particles together" to provide "99 to 100 percent" coverage on internal engine surfaces.

Other companies take non-PTFE approaches to the problem. For instance, First Brands' STP Engine Treatment uses a formula it calls XEP2, composed of various agents, which is also claimed to bond to internal engine surfaces. Castrol's Syntec FSX contains a negatively charged chemical ester that is said to bond molecularly with positively charged engine parts and uses a 5W-50 synthetic carrior oil. Power Up employs NNL-690, a lubricant that reportedly changes from a liquid to a solid (in the form of minute particles) as the conditions change from light to heavy loads.

So how can you tell what works and what doesn't? In most cases buyers need to sift through the literature and try to read between the lines; not exactly a reliable method. So it was with interest that we met with representatives from Petrolon, who brough stacks of hard numbers from an extensive series of tests conducted last year. Here are the details in a nutshell.

The tests were done by Southwest Research Institute, in San Antonio, Texas, an independent facility monitored by the American Society for Testing and Materials (ASTM). Two different tests were conducted at a cost of about $1 million: a start/stop test and a continuous operation test, each designed to simulate 50,000 miles worth of operation.

The tests were extended versions of a Sequence IIIE test, a widely accepted automotive and petroleum procedure for motor oils that simulates stressful highway driving. Six industry-standard Buick V-6 engines were used for each phase; three were treated with Slick 50, and three were not, to serve as controls. A 5W-30 SG premium-quality oil was used in all engines.

The parts to be examined, including piston rings, rocker arms, and connecting rod and main bearings, were weighed both before and after the tests to determine the amount of wear.

In the start/stop test, the engines were started, idled for one minute, accelerated to the equivalent of 50 mph for 10 minutes to simulate a short trip, and then turned off. A total of 330 such repetitions were performed. Then the oil and filter were changed (no new Slick 50 was added), and the engines run for four hours at the equivalent of 70 mph to flush them. The oil was drained and the filter removed. Then a series of 500 start/stop sequences were conducted without oil to simulate dry starts, in which the engine was started, revved to 1000 rpm, and shut off.

In the continuous-operation test, the engines were run for 480 hours at 3000 rpm, which is estimated to simlulate 50,000 miles. The oil and filter were changed every 3000 miles with Slick 50 added to the appropriate engines during only the first oil change.

After both test were completed, all engines were disassembled and measured for wear. The following results show the average reduction of wear in the parts used in the Slick 50-treated engines:

Start/Stop Rod bearings .................... 55 percent Main bearings ................... 34 percent Piston rings .................... 43 percent Rocker arms ..................... 22 percent Average of all parts ............ 39 percent

Continuous Operation Rod bearings .................... 44 percent Main bearings ................... 8 percent Piston rings .................... 25 percent Rocker arms ..................... 18 percent Average of all parts ............ 24 percent

Petrolon noted that anti-wear protection was best between 10,000 and 50,000 miles, though there was no way to project within this testing format whether more frequent PTFE treatments would've given better results.

According to these tests, Slick 50 provides significant anti-wear benefits. Many other companies, however, lack the funds to verify their products' claims to conclusively. Therefore, common sense should be used when shopping.

* Approach claims of "life-time treatments" and specific percentage increases in mileage or performance with a healthy skepticism. Even if better gas mileage or performance is technically true, the improvements will likely be subtle.

* PTFE is inert, won't melt at engine temperatures, and has virtually no expansion rate. Beware of claims that contradict these properties.

* If a PTFE product requires you to shake the can, the particles likely will separate and settle into your oil pan. Avoid these compounds.

* Remember that the anti-wear benefits of these engine treatments won't provide a payoff until many miles down the road. If you're the type that gets a new car every five years, then it likely will be future owners who'll thank you for using an anti-wear product. However, if you keep vehicles for a long time, then a friction-reducing formula may be worth the investment.

------------------------------------------------------------------------ Joel's commentary: 1. If it is so great, which departments of the government and/or industry use it? seems like the army/air force/navy would be very interested in something like this, especially for helicopter or aircraft engines, or ship engines. what about diesel locomotives, that basically run ALL the time?

Remember now, we are talking about the same government that spent several millions of dollars to test if Bovine Flatulence was affection the ozone layer. surely they wouldn't be 'cowed' by a little oil test. ;)

2. "Petrolon noted that anti-wear protection was best between 10,000 and 50,000 miles ..." how did they come up with this, based on the tests that were described? it didn't say that they disassembled the engine at 10,000 miles. so how do they know the protection was 'best' at that mileage?

3. If PTFE treatment WAS of any value, do you really think that DuPont would miss out on such an opportunity to market their own product, especially since they own the patent rights to PTFE (Teflon)? Something about this doesn't quite fit the standard practices of large american corporations, does it? :)

4. I remain unconvinced.

joel


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